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Next Patent: Shelf assembly
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[0001] This application is a continuation-in-part to an application filed on Mar. 13, 2000, application Ser. No. 09/524,578.
[0003] This invention relates in general to systems for removing contaminants from liquids and, more specifically to a system for removing toxic chemicals and volatile gases (such as methyl tertiary butyl ether [MTBE], benzene, trihalomethanes, and the like), volatile chemical contaminants, pesticides, particles such as algae, other suspended organic and inorganic solids, chemicals, dissolved oils, and other particles including large and heavy particles and light, fine, or buoyant particles from water.
[0004] This present invention relates to an improvement in a pretreatment filtration system which removes most contaminants from raw influent water before the water to be processed enters the treatment plant filtration system.
[0005] Proper water treatment and filtration are major concerns for the health and safety of all inhabitants where ever located. Improper treatment and/or disposal causes health problems, disease, and even death. The Center for Disease Control (CDC), through DNA tests, identified human sewage as the source of the 1993 Milwaukee, Wis., Cryptosporidium parvum parasite outbreak that infected over 400,000 people in that city. In the latest issue of the CDC's, Emerging Infectious Diseases Journal, the results are reported on the molecular analysis of 39 isolates of Cryptosporidium parvum from human and bovine sources in nine human outbreaks, including isolates from the 1993 Milwaukee outbreak. The new study suggests that the source of the parasite Cryptosporidium parvum in the Milwaukee outbreak is human, not bovine.
[0006] Four stool specimens were examined from the Milwaukee outbreak: three from the original outbreak and a fourth from an AIDS patient in 1996 who had initially been infected in the 1993 outbreak. All four were found only in isolates from humans. None of the four isolates were capable of producing an infection in laboratory animals.
[0007] Animal waste was also identified by DNA tests as the source of the Canadian
[0008] Canadian municipalities must release their first public water quality reports by Oct. 30, 2000. Municipalities that violate the rules face fines ranging from $20,000 to $2 million. Jail sentences can also be imposed. This new regulation establishes tougher drinking water standards and policies that reflect the most current expertise and procedures in drinking water protection. Additionally, the U.S. Consumer Confidence Report requires every public water utility to distribute a detailed analysis of the chemicals, parasites, bacteria and virus in their public water supply for the previous year to all homeowners. These water quality reports are increasing the demand for better technology that works.
[0009] All public water districts using surface water must install filtration equipment and hire a State certified grade-3 plant operator by the year 2003, which is the Clean Water Act regulations deadline for small water districts. The largest immediate market for pre-filtration systems are in those states with the highest number of small water districts using surface water. Efficient and effective pre-filtration systems are a mandated necessity under current regulations/requirements. The pre-filtration system of the present invention meets, and exceeds, the challenges imposed by these regulations/requirements and far surpasses current pre-filtration systems in that challenge.
[0010] Water supplies for domestic drinking water, process water for chemical plants, or other liquids are often contaminated with a variety of contaminants, such as, but not limited to, toxic chemicals, volatile chemical contaminants (such as MTBE, benzene, perchlorate, trihalomethanes, and the like), pesticides, particles such as algae, other suspended organic and inorganic solids, dissolved oils, and other particles including large and heavy particles and light, fine, or buoyant particles (referred to collectively as contaminants). These contaminants must be removed in a reliable and cost-effective, cost-efficient manner.
[0011] The pre-filtration water decontamination system of the present invention was designed to remove most of the organic suspended solids (such as, but not limited to, algae), and volatile toxic chemicals from the raw influent water before it enters a final-stage treatment plant filtration system. Pre-filtration is necessary for a more efficient operation of the final-stage filtration. Common pre-filtration systems include use of sand filters, membrane filters, chemical flocculation-sedimentation-filtration (settle-to-the-bottom method), and large tank-type dissolved air flotation (DAF) systems. These systems and methods do work at pre-filtration but are not as effective nor as efficient as is necessary for proper pre-filtration.
[0012] Many older water treatment plants use gravitational separation methods, typically in sedimentation systems or dual-media sand filtration systems that may not be acceptable under the newer water quality standards. In some cases, these systems can meet the standards through the use of properly mixed polymer chemical filter aids. The required expensive and complex polymer chemical mixing equipment requires constant attention, since the amount of the chemicals being added to raw water must be frequently readjusted to match the continually changing chemistry of the water being filtered. Slow sand filters require a considerable investment, but generally can be operate for longer periods without cleaning. Unfortunately, even with pretreatment, both dual-media and slow sand filters fail to meet water quality standards for hours or several days after each backwash cleaning. Ordinary sand filters become overwhelmed after every rainstorm. Membrane filters, which generally are more efficient than sand filters, quickly clog and require constant attention whenever it rains. The system of the present invention actually becomes more efficient when turbidity increases.
[0013] Ordinary chemical flocculation and sedimentation processes are slow, require chemicals, and their maintenance is high. Moreover, they do not prevent toxic chemicals, pesticides and algae from passing through the ordinary filter bed. If algae spores, for example, are present when chlorine is added, toxic disinfection byproducts are formed, which is highly undesirable and a violation of the USEPA Safe Drinking Water Act. The inability of older municipal filtrations systems to remove algae is apparent in the lack of clarity found when a swimming pool is filled with “clean” tap water. Most pool contractors have to shock tap water with large doses of chlorine chemical pool oxidizer to achieve the desired clear pool water appearance.
[0014] Some decontaminating systems, such as air stripping towers, currently discharge toxic chemical gases and volatile organic compounds into the atmosphere. Particulate material has also been removed from liquids by DAF floatation, another gravitational method, in which bubbles of a gas, such as air or oxygen, are introduced into the lower levels of the liquid and float to the top, carrying fine particles with them. These systems rely heavily on chemicals whereby chemical flocculates and microscopic air bubbles slowly float to the surface of a large flotation tank. This system is very costly and cumbersome requiring chemical mixers to blend flocculating chemicals such as alum (aluminum) with the raw influent before it enters a main tank. A large impeller pump injects high-pressure water containing excess dissolved air through an array of jet nozzles in the bottom of the tank. Mechanical scrapers push the float particles into a trough for removal and dewatering. These are relatively inefficient, in light of the outbreaks abovedescribed, costly to operate and maintain, and require proper treatment and/or dispose of chemical residues and by-products.
[0015] Flotation is a gravitational method because the rise of bubbles is due to the gravitational acceleration acting on the mass of the liquid in accordance with the basic force equals mass time acceleration relationship. A force balance relative to a pocket of gas phase within liquid (a bubble), where the mass of the bubble is its volume times its density, shows that the bubble must rise to find equilibrium, because the density of a gas is generally less than that of a liquid. Large flotation tanks are required to allow adequate time for air bubbles to reach the surface.
[0016] Failure to remove all contaminants prior to filtration also leads to clogged filters, increases filter operation costs and wastes water required for frequent filter cleaning cycles. The use of flocculation promoting chemicals increases the volume of sludge to be dewatered and removed.
[0017] Thus, there is a continuing need for a pre-filtration (or pretreatment) separation system that will rapidly, efficiently, and effectively remove particles and volatile gases from liquids while treating a liquid, will efficiently remove algae and volatile gases (all contaminants) during pretreatment prior to filtration and will reduce overall treatment costs and conserves water through less frequent filter cleaning and a smaller sludge volume.
[0018] The present invention uses micro-bubbles with ionized ordinary ambient air (to form micro-bubbles) which basically blend with raw process water (raw influent). These micro-bubbles attach to suspended particles (contaminants) of the raw influent and are quickly removed from the water stream with a hydrocyclone vortex extraction column (separator). This extraction method is simple and environmentally friendly. No aluminum chemicals are used, which as a result reduces the volume of sludge to be disposed of in landfills. By simply removing most of the contaminants from the process water stream, the present invention prevents the formation of toxic chemical byproducts when necessary chlorine residuals are added to prevent bacterial regrowth in the community distribution system.
[0019] After removal of the contaminants, decontaminated water (which has been separated from the raw influent) is discharged to the filtration system and the waste water is discharged to a recovery system for recovery and removal of disposable and/or any recyclable waste (sludge) and re-processing of remaining waste water back through the system. This pre-filtration system was designed to remove contaminants from raw influent before it enters the treatment plant filtration system. It is simple, efficient, effective, low in maintenance, and environmentally friendly. No chemicals are used, which thereby reduces the volume of sludge to be disposed of in landfills. Removing most of the contaminants from the raw influent prevents the formation of toxic chemical disinfection byproducts, formed when chlorine chemical residuals are added to other systems to prevent bacterial re-growth in community water distribution systems.
[0020] Accordingly, several objects and advantages of my invention are to:
[0021] a. establish a pre-filtration system which is low in cost, easy to install, and easy to maintain;
[0022] b. provide a pre-filtration system which is relatively compact in size;
[0023] c. dramatically reduced replacement costs for a pre-filtration system;
[0024] d. provide for a pre-filtration system which is extremely efficient in separating waste matter, solids and gases, from an influent stream;
[0025] e. to minimize or eliminate the use of chemicals and toxins in a pre-filtration system; and
[0026] f. more safely and effectively pre-treat influent.
[0027] The foregoing has outlined some of the more pertinent objects of the present invention. These objects should be construed to be merely illustrative of some of the more prominent features and applications of the intended invention. Many other beneficial results can be attained by applying the disclosed invention in a different manner or by modifying the invention within the scope of the disclosure. Accordingly, other objects and a fuller understanding of the invention may be had by referring to the summary of the invention and the detailed description of the preferred embodiment in addition to the scope of the invention defined by the claims taken in conjunction with the accompanying drawings.
[0028] The above-noted problems, among others, are overcome by the present invention. Briefly stated, the present invention contemplates a pre-filtration water decontamination apparatus having an oxygen saturator for introducing high-pressure air and a high-pressure ozone-treated ionized water mixture therein and to substantially saturate this high-pressure treated/ionized water mixture with excess oxygen thereby creating a high-pressure oxygenated mixture (HPOM) stream; a blender for receiving and mixing the HPOM stream from the oxygen saturator with influent water containing contaminants to be removed; means for directing the HPOM stream from the oxygen saturator, at a pre-determined pressure, to the blender, and means for directing influent water to the blender at a lower pressure such that a white-water process (WWP) stream comprising a plurality of micro-bubbles is created in the blender; a separator for receiving the WWP stream from the blender and having means for causing upward vortex rotation of the WWP stream, for separating from the WWP stream a waste water stream along a central axis of the upward vortex of the separator, and for separating from the WWP stream a decontaminated water (DCW) stream along an outer wall of the separator; and a recovery unit for directing discharge of the DCW stream out of the apparatus through a water outlet, and for directing disposition of the waste water stream out of the apparatus for re-processing and for recycling.
[0029] The foregoing has outlined the more pertinent and important features of the present invention in order that the detailed description of the invention that follows may be better understood so the present contributions to the art may be more fully appreciated. Additional features of the present invention will be described hereinafter which form the subject of the claims. It should be appreciated by those skilled in the art that the conception and the disclosed specific embodiment may be readily utilized as a basis for modifying or designing other structures and methods for carrying out the same purposes of the present invention. It also should be realized by those skilled in the art that such equivalent constructions and methods do not depart from the spirit and scope of the inventions as set forth in the appended claims.
[0030] Details of the invention, and of preferred embodiments thereof, will be further understood upon reference to the drawings, wherein:
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[0038] A flow chart for the pre-filtration water decontamination system of this invention is provided in
[0039] Next the concentrated oxygen enters a conventional corona discharge type ozone generator
[0040] A conventional hi-pressure pump
[0041] The HPOM (designated by flow arrow X in
[0042] The WWP stream is discharged (as designated by flow arrow Y in
[0043] At the top of the separator
[0044] The entire system is programmed with conventional software and monitored and controlled by one or more nodes (tank node
[0045] Typical products, or their equivalent, include for the nodes, Model/Part Number EC230 distributed by CNA Engineers, Singapore; for the pressure sensors, Model/Part Number MSP600250-P-5-D-4 distributed by Measurement Specialities, Inc., of Valley Forge, Pa.; for current sensors, Model/Part Number HA 10-NP, LTS 25-NP, HY 50-P, or HAL 50-S distributed by LEM USA, Inc., of Milwaukee, Wis.; for the high-pressure pump, Model/Part Number 10GBC20 distributed by Barrett Pump of San Diego, Calif.; for the air compressor, Model/Part Number Emgio 283MK 15A8P distributed by White Cap of San Diego, Calif.; for the flow meters, Model/Part Number V2-M1A300F300-E3-X1-25 or V2-M1-A100F50-E3-X1-25 distributed by Asahi-America of Malden, Mass.; for the valves, Model/Part Number 509F distributed by Inline Industries; and for the valve actuators, Model/Part Number 509-20S8-3LA-TRIM-01 distributed by Bettis Actuators and Controls.
[0046] The entire process is controlled by a conventional communication hardware and software. The protocol used in the present invention is an Echelon LonWorks® digital network; though any equivalent communication hardware and software suited for the intended purpose will suffice. The control software programs are distributed among the various control nodes
[0047] The pre-filtration water decontamination system and apparatus, as represented in
[0048] The high-pressure water stream percolates down through packed fill material
[0049] The sensor assembly
[0050] The high-pressure water stream becomes saturated with excess oxygen in this environment and under these conditions. When the air envelop ‘shrinks’ as it is adsorbed by ionized ozone-treated water cascading through the fill material
[0051] The flow distributor
[0052] Additionally, where each section
[0053] The functionality of the flow distributor
[0054] After the high-pressure water stream (which includes high-pressure ionized ozone-treated water mixture) is fully oxygen-saturated (containing excess dissolved oxygen; approximately 50-90 mg/l) it exits the oxygen saturator
[0055] Reference is now made to
[0056] The disk pump
[0057] Other pumps use some type of impingement device, relying on force to push the water through the pump. Ordinary impeller pumps shear the polar bond of the micro-bubbles and the formed and forming clusters of particles (contaminants) and microbubbles. This causes the micro-bubbles to separate from the microscopic solid particles of the raw influent before they can be discharged to the separator. The non-impingement and laminar flow of the disk pump
[0058] Additionally, disk pumps actually perform more efficiently when pumping algae-laden water. Water containing dense concentrations of algae will cling more readily to the disk surface, which increases disk pump flow rates. The variable speed controller for the motor
[0059] The viscous-drag of the smooth surfaces of the disk pump
[0060] With regard to the white-water phenomenon, as the HPOM stream (which contains excess dissolved oxygen) is injected into a low-pressure environment, the excess dissolved oxygen immediately expands to form billions of “invisible” micro-bubbles (over 400 million microscopic air bubbles per gallon). The total surface area of the micro-bubbles within one-gallon of white-water is approximately 250,000 square feet. The oxygen inside the micro-bubbles refracts white on the color scale, giving the opaque raw influent a chalk-white appearance, which is why the result is called “white-water.” The ratio of the HPOM stream, and its white-water, to that of raw influent to create a overall white-water effect (of the HPOM stream and raw influent) is about 10% to 15% HPOM stream to the raw influent.
[0061] Additionally, air bubbles in the range of a one-micron diameter (or smaller) have little buoyancy and will remain stationary unless external forces are applied to them. Microscopic solid particles (contaminants in the raw influent) also remain stationary in water and rarely collide with adjacent micro-bubbles unless there is a polar attraction. Micro-bubbles which do collide with other adjacent micro-bubbles form increasingly larger bubbles, which eventually become sufficiently buoyant to slowly rise to the surface (this is the process used for a tank-type DAF floatation system and is precisely why very large dissolved-air flotation tanks are required for its process).
[0062] If, however, the micro-bubbles are ionized (as in the system and apparatus of the present invention), hundreds of positively charged micro-bubbles will attach themselves to the negatively charged microscopic solid particles (contaminants) contained within the raw influent thereby coating the contaminants and creating numerous multi-micro-bubble combinations (containing the contaminants) in the process. These newly formed multi-micro-bubble combinations then collide with, and attach to, each other thereby forming increasingly larger clusters upon clusters of such combinations. These newly formed larger clusters become buoyant and will begin to rise slowly to the surface. As these larger clusters so rise they collide with, and attach to, other similar large clusters, thereby increasing in size and in buoyancy in the process. The attaching process repeats and repeats throughout the process and the buoyancy of the clusters increases with their size.
[0063] The plurality of blender inlet slots
[0064] The WWP stream fills the blender
[0065] The WWP stream enters the separator
[0066] By this configuration, an upward vortex column (or vortex column) is created and laminar viscous-drag separation is achieved in the process. In this regard, when the WWP stream (high-pressure water containing excess dissolved oxygen blended into the raw influent stream) is subjected to centrifugal forces inside a separator
[0067] Unlike a large, deep flotation tank as in the prior art, the distance between the outer perimeter and the center of the vortex column in the separator
[0068] The low pressure at the center of the vortex column causes the microscopic solid particles (contaminants) of the WWP stream to coalesce in the center as the waste water stream. The high pressure at the perimeter of the separator
[0069] The waste water stream is carried to the top of the separator
[0070] Prior art air stripping towers currently discharge toxic chemical gases and volatile organic compounds into the atmosphere. When the carbon filter
[0071] The recovery unit
[0072] After the waste filter
[0073] At this point, the water generally has had nearly all contaminants removed and can be passed to a conventional water plant filtration system via output pipe to remove any remaining particles. This pre-filtration process removes between 80.099.999% (5-log) of the suspended solids from the treatment plant process water flow; most regularly, such removal normally ranges above 99.99% (4-log). Also, substantially all algae is removed. This is sufficient to meet present US EPA Clean Water Act regulations for a minimum 85% removal of suspended solids.
[0074] The operation, by volume and time, of the system described herein, under the examples set forth below, not as limitations to the present invention, would be as follows. Where the total volume of space between the upper ultrasonic-sensor and the lower ultrasonic-sensor inside the top of the separator column is 105.7 in.
[0075] Also by way of example only, not by way of limitation, a 400 mg/l (ppm) concentration of buoyant suspended solids in a 100 GPM raw influent stream flow would be equal to approximately 0.2 pounds of suspended solid waste every hour, or 0.0267 ft.
[0076] The above example reflects only that based on contaminant concentrations, volumes, and desired results. The results can easily be varied by the software based on the contaminant concentrations and types, and volumes being received or desired.
[0077] It must also be understood that the apparatus and its components parts may be constructed of any material suited for the intended purpose. Preferably from materials approved and acceptable for potable water by the National Sanitation Foundation (NSF). Such materials included, but are not limited to, plastics, machined metal, cast metal, or the equivalents, or any combinations thereof.
[0078] The present disclosure includes that contained in the present claims as well as that of the foregoing description: Although this invention has been described in its preferred forms with a certain degree of particularity, it is understood that the present disclosure of the preferred form has been made only by way of example and numerous changes in the details of construction and combination and arrangement of parts and method steps may be resorted to without departing from the spirit and scope of the invention. Accordingly, the scope of the invention should be determined not by the embodiment[s] illustrated, but by the appended claims and their legal equivalents.